86043-05-2Relevant academic research and scientific papers
Arylcyclopropane Photochemistry. Effects of Electron-Donating and Electron-Withdrawing Aromatic Substituents on the Photochemical Rearrangements of 1,1-Diarylcyclopropanes.
Hixson, Stephen S.,Franke, Lothar A.
, p. 2706 - 2711 (2007/10/02)
Irradiation of 1,1-diarylcyclopropanes 4a-g, having substituents X and Y at the para positions of the aromatic rings, afforded 1,1-diarylpropenes 5a-g and 1-arylindans 6a-f.The rate constants of these (singlet state) reactions, determined from the reactan
ARYLCYCLOPROPANE PHOTOCHEMISTRY. SUBSTITUENT EFFECTS ON THE PHOTOCHEMICAL CONVERSION OF 1,1-DIARYLCYCLOPROPANES TO 1,1-DIARYLPROPENES AND 1-ARYLINDANES.
Hixson, Stephen S.,Franke, Lothar A.
, p. 41 - 44 (2007/10/02)
The rate of photochemical rearrangement of 1,1-diarylcyclopropanes to 1,1-diarylpropenes and 1-arylindanes is enhanced by electron-withdrawing groups on the aromatic rings and diminished by electron-donating groups.
