860453-04-9

Basic information

• Product Name: [((C₆H₅)3P)AuCCC(CH₃)(OH)C₆H₅]
• CAS NO: 860453-04-9
• Molecular Weight: 604.438
• Mol File: 860453-04-9.mol

Chemical Properties

• CAS DataBase Reference: [((C₆H₅)3P)AuCCC(CH₃)(OH)C₆H₅](CAS DataBase Reference)
• NIST Chemistry Reference: [((C₆H₅)3P)AuCCC(CH₃)(OH)C₆H₅](860453-04-9)
• EPA Substance Registry System: [((C₆H₅)3P)AuCCC(CH₃)(OH)C₆H₅](860453-04-9)

Safety Data

• Hazardous Substances Data: 860453-04-9(Hazardous Substances Data)

Upstream product

• 860452-98-8 Au⁽¹⁺⁾*CCC(CH₃)(OH)C₆H₅^(1-)=[AuCCC(CH₃)(OH)C₆H₅] 
• 603-35-0 triphenylphosphine 

Relevant articles and documents

Use of phosphine gold acetylides [(R3P)AuC≡CR] to form phosphine gold derivatives of tetra-iron and penta-iron clusters

Five new gold acetylides, [AuCCR], with hydroxyl or amino functions in the organic radical R have been prepared. From these, nine phosphine complexes [(R3P)AuCCR] with R = Ph or Cy were synthesised. Reactions between the phosphine gold acetylides [(Ph3P)AuCCC(Me)(OH)Et] or [(Cy 3P)AuCCC(Me)(OH)Et] and the iron carbonyl cluster [Et 4N][Fe4N(CO)12] gave both neutral [(R 3P)AuFe4N(CO)12] and ionic compounds [(R 3P)2Au][Fe4N(CO)12]. Reaction with the penta-iron cluster [Et4N][Fe5N(CO)14] afforded [(R3P)2Au][Fe5N(CO)14], [(R3P)2Au][Fe4N(CO)12] and [(R 3P)AuFe4N(CO)12]. The gold-iron clusters were characterised with spectroscopic methods (IR, NMR and M?ssbauer) and in the case of [(Cy3P)AuFe4N(CO)12] a single-crystal X-ray analysis.