86047-42-9Relevant articles and documents
New accessible ways to 2-ethoxycarbonylallylphosphonates
Mrabet, Hedi,Zantour, Hedi
, p. 25 - 33 (2004)
The Michaelis-Arbusov reaction (method A) and the nucleophilic addition of dialkylphosphites followed by Hoffman olefination (method B) represent two synthetic methods giving a variety of 2-ethoxycarbonylallyl-phosphonates 2, in good yields, from readily accessible ethyl 2-(N,N-dialkylaminomethyl) acrylates 1.
Facile synthesis of bisphosphine monoxides from Morita–Baylis–Hillman carbonates
Zhou, Rong,Zhang, Kai,Liu, Rongfang
, p. 885 - 890 (2016/07/06)
A facile two-step synthesis of bisphosphine monoxides (BPMOs, with both the phosphine and phosphine oxide moieties within one molecule) from readily available Morita–Baylis–Hillman (MBH) carbonates was realized. Under the catalysis of DABCO, the MBH carbo
Synthesis of a functionalized allylic phosphine oxide
Harmata, Michael,Carter, Kevin W.
, p. 3027 - 3033 (2007/10/03)
A functionalized allylic phosphine oxide has been prepared by regioselective bromination of 2-(methyldiphenylphosphinoyl)-1-propene followed by nucleophilic substitution with acetate. Hydrolysis and protection yielded the target compound.