86051-57-2Relevant academic research and scientific papers
Selectivity in Vinyl Azide Reactions; Decomposition of Azidocinnamates with Olefinic ortho-Substituents
Hickey, Deirdre M. B.,Moody, Christopher J.,Rees, Charles W.
, p. 1419 - 1421 (1982)
Thermal decomposition of vinyl azides (1a - c) gives isoquinolines (3), benzazepines (4), or aziridines (5) and (6) by preferential reaction at the unsaturated substituent; removal of this unsaturation as in the epoxides (1d, 1e) leads exclusively to 4-substituted indoles.
Vinyl Azides in Heterocyclic Synthesis. Part 2. Selectivity in the Decomposition of Azidocinnamates with Olefinic ortho-Substituents
Hickey, Deirdre M. B.,Moody, Christopher J.,Rees, Charles W.
, p. 1113 - 1118 (2007/10/02)
Thermolysis of azidocinnamates with an olefinic o-substituent gives products (isoquinolines, azepines, aziridines) formed by selective interaction of the azide, and the derived nitrene, with the olefinic substituent, cyclisation onto the unsubstituted aro
