86053-35-2Relevant academic research and scientific papers
Atrane Analogous Compounds of Type (I)
Grobe, Joseph,Voulgarakis, Nikolaos
, p. 269 - 279 (2007/10/02)
Heterocyclic ring compounds of type I (compounds 9 and 10) have been prepared by condensation reactions of α,ω-difunctional derivatives XMe2SiCH2M'Me2X (X = Cl, NMe2; M' = Si, Sn) with N-methyldiethanolamine using the "Dilution Principle".The starting compounds XMe2SiCH2M'Me2X are obtained by reacting XMe2SiCH2MgCl with ClM'Me2X (Scheme, Abb. 1).The existence of transanular N->Si or N->M' interactions depends on the N-M distance and the acidity of the acceptor atoms.In order to clarify the weight of these factors acyclic analoga of compounds 9 and 10 have been prepared. - Key words: Silatrane, Stannatrane, Transanular N -> M - Interaction, NMR Data
