860587-67-3Relevant academic research and scientific papers
Pd/C-Catalyzed Aminocarbonylation of Aryl Iodides with Anthranils in Water Using Mo(CO)6 as the CO Source
Wang, Zechao,Yin, Zhiping,Wu, Xiao-Feng
supporting information, p. 15026 - 15029 (2017/10/18)
A convenient procedure for the synthesis of N-(2-carbonylaryl)benzamides has been developed. Through Pd/C-catalyzed aminocarbonylation of anthranils with various hindered and functionalized aryl iodides, the desired amides were afforded in moderate to good yields. The protocol is advantageous due to the recyclable Pd/C catalyst, safe Mo(CO)6 as the solid CO source, and environmentally benign water as solvent. No inert atmosphere protection is needed.
KOtBu-mediated stereoselective addition of quinazolines to alkynes under mild conditions
Zhao, Dan,Shen, Qi,Zhou, Yu-Ren,Li, Jian-Xin
supporting information, p. 5908 - 5912 (2013/09/12)
A facile alkenylation of quinazolines with unactivated terminal alkynes has been achieved in the presence of KOtBu without the aid of any transition metal catalysts. The reaction is carried out under very mild conditions and shows a high stereoselectivity
