860652-04-6

Basic information

• Product Name: (diethoxyphosphoryl)acetic acid (R)-4-((2R,6R)-{6-((2E,4S,6Z)-[4-(4-methoxybenzyloxymethoxy)-6-methyl-8-oxoocta-2,6-dienyl])-4-methylenetetrahydropyran-2-yl})-1-(4-methoxybenzyloxymethyl)-[(E)-3-methylbut-3-en]yl ester
• Synonyms: (diethoxyphosphoryl)acetic acid (R)-4-((2R,6R)-{6-((2E,4S,6Z)-[4-(4-methoxybenzyloxymethoxy)-6-methyl-8-oxoocta-2,6-dienyl])-4-methylenetetrahydropyran-2-yl})-1-(4-methoxybenzyloxymethyl)-[(E)-3-methylbut-3-en]yl ester
• CAS NO: 860652-04-6
• Molecular Weight: 812.935
• Mol File: 860652-04-6.mol

Chemical Properties

• CAS DataBase Reference: (diethoxyphosphoryl)acetic acid (R)-4-((2R,6R)-{6-((2E,4S,6Z)-[4-(4-methoxybenzyloxymethoxy)-6-methyl-8-oxoocta-2,6-dienyl])-4-methylenetetrahydropyran-2-yl})-1-(4-methoxybenzyloxymethyl)-[(E)-3-methylbut-3-en]yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (diethoxyphosphoryl)acetic acid (R)-4-((2R,6R)-{6-((2E,4S,6Z)-[4-(4-methoxybenzyloxymethoxy)-6-methyl-8-oxoocta-2,6-dienyl])-4-methylenetetrahydropyran-2-yl})-1-(4-methoxybenzyloxymethyl)-[(E)-3-methylbut-3-en]yl ester(860652-04-6)
• EPA Substance Registry System: (diethoxyphosphoryl)acetic acid (R)-4-((2R,6R)-{6-((2E,4S,6Z)-[4-(4-methoxybenzyloxymethoxy)-6-methyl-8-oxoocta-2,6-dienyl])-4-methylenetetrahydropyran-2-yl})-1-(4-methoxybenzyloxymethyl)-[(E)-3-methylbut-3-en]yl ester(860652-04-6)

Safety Data

• Hazardous Substances Data: 860652-04-6(Hazardous Substances Data)

Upstream product

• 858917-00-7 ethyl (2E,5R)-6-[(4-methoxyphenyl)methoxy]-3-methyl-5-(1,1,2,2-tetramethyl-1-silapropoxy)hex-2-enoate 
• 439143-41-6 (2E)(5R)-6-[(4-methoxyphenyl)methoxy]-3-methyl-5-(tert-butyldimethylsilyloxy)hex-2-enal 
• 439143-40-5 ethyl (2E)-(5R)-5-hydroxy-6-[(4-methoxyphenyl)-methoxy]-3-methylhex-2-enoate 
• 824-94-2 p-methoxybenzyl chloride 
• 121289-23-4 p-methoxybenzyloxyacetaldehyde 
• 131489-39-9 1-<(trimethylsilyl)oxy>-1-ethoxy-3-methyl-1,3-butadiene 
• 638-10-8 ethyl 3-methylbut-2-enoate 
• 1027836-36-7 (2R,6S)-2-[(E)-(R)-4-(tert-Butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-2-methyl-pent-1-enyl]-6-[(3E,6Z)-(S)-8-(tert-butyl-diphenyl-silanyloxy)-6-methyl-2-phenylselanyl-octa-3,6-dienyl]-4-methylene-tetrahydro-pyran 
• 860651-96-3 {2-((4R,6S)-[(R,E)-4-(tert-butyldimethylsilanyloxy)-5-(4-methoxybenzyloxy)-2-methylpent-1-enyl]-6-[(1E,4Z)-6-(tert-butyldiphenylsilanyloxy)-4-methylhexa-1,4-dienyl]-[1,3]dioxan-4-yl)}acetic acid butyl ester 
• 860651-97-4 (2S,3E,6Z)-1-((2S,6R)-{6-(R,E)-[4-(tert-butyldimethylsilanyloxy)-5-(4-methoxybenzyloxy)-2-methylpent-1-enyl]-4-methylenetetrahydropyran-2-yl})-8-(tert-butyldiphenylsilanyloxy)-6-methylocta-3,6-dien-2-ol 
• 860651-98-5 (2E,4S,6Z)-1-((2R,6R)-{6-(R,E)-[4-(tert-butyldimethylsilanyloxy)-5-(4-methoxybenzyloxy)-2-methylpent-1-enyl]-4-methylenetetrahydropyran-2-yl})-8-(tert-butyldiphenylsilanyloxy)-6-methylocta-2,6-dien-4-ol 
• 860652-03-5 (S,2Z,6E)-5-((4-methoxybenzyloxy)methoxy)-8-((2R,6R)-6-((R,E)-5-(4-methoxybenzyloxy)-4-hydroxy-2-methylpent-1-enyl)tetrahydro-4-methylene-2H-pyran-2-yl)-3-methylocta-2,6-dien-1-ol 
• 1027166-75-1 (6E,9Z)-(3R,5S)-11-(tert-Butyl-diphenyl-silanyloxy)-9-methyl-3,5-bis-trimethylsilanyloxy-undeca-6,9-dienoic acid butyl ester 
• 860651-88-3 (3R,5S,6E,9Z)-11-(tert-butyldiphenylsilanyloxy)-3,5-dihydroxy-9-methylundeca-6,9-dienoic acid butyl ester 

Downstream Products

• 860652-00-2 (1R,2E,5R,8E,10Z,13S,14E,17R)-13-((4-methoxybenzyloxy)methoxy)-5-((4-methoxybenzyloxy)methyl)-3,11-dimethyl-19-methylene-6,21-dioxabicyclo[15.3.1]henicosa-2,8,10,14-tetraen-7-one 

Relevant articles and documents

Total synthesis of (+)-dactylolide through an efficient sequential peterson olefination and prins cyclization reaction

(Chemical Equation Presented) Key steps in the total synthesis of the macrolide natural product (+)-dactylolide (see formula) include two enantioselective vinylogous Mukaiyama reactions, fragment coupling through acetal formation, a sequential Peterson ol