860653-35-6Relevant academic research and scientific papers
Enantioselective total synthesis of (+)-gliocladin C
Overman, Larry E.,Shin, Youseung
, p. 339 - 341 (2007/10/03)
(Chemical Equation Presented) The first total synthesis of gliocladin C, a fungal-derived marine alkaloid containing a rare trioxopiperazine fragment, is reported. This asymmetric synthesis establishes the absolute configuration of this structurally novel
Asymmetric construction of quaternary carbon stereocenters: High stereoselection in Mukaiyama aldol reactions of 2-siloxyindoles with chiral aldehydes
Adhikari, Susanta,Caille, Sebastien,Hanbauer, Martin,Ngo, Vinh X.,Overman, Larry E.
, p. 2795 - 2797 (2007/10/03)
(Chemical Equation Presented) A new synthesis of enantiopure 3,3-disubstituted oxindoles by stereoselective Mukaiyama aldol reaction of 3-substituted 2-siloxyindoles and chiral, enantiopure aldehydes having nitrogen or oxygen substituents at the α carbon
