86071-72-9Relevant academic research and scientific papers
Metallocene compound containing indenoindole structure, preparation method and application thereof, and preparation method of alpha-olefin
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Paragraph 0128; 0154; 0158-0160, (2021/06/09)
The invention provides a metallocene compound containing an indenoindole structure, a preparation method and application thereof, and a preparation method of alpha-olefin. The metallocene compound containing the indenoindole structure provided by the invention has a structure as shown in a formula (A) or a formula (B), can be used as a catalyst for catalytic synthesis of alpha-olefin, and can be used for high-activity and high-selectivity synthesis of high-carbon-number alpha-olefin, and the main components in the product are 1-octene, 1-decene and 1-dodecene.
Alternative Ligands, XIV. - Novel Chelating Ligands of the Type (2-Me2E'C6H4)Si(EMe2)Me2 (E, E' = N, P, As; Me = CH3)
Aslanidis, Paraskevas,Grobe, Joseph
, p. 280 - 288 (2007/10/02)
Chelating ligands of the type (2-Me2NC6H4)Si(EMe2)Me2 (E = N, P, As) are prepared by ortho-lithiation of N,N-dimethylaniline followed by reaction with ClSi(NMe2)Me2 to yield (2-Me2NC6H4)Si(NMe2)Me2.Cleavage of the SiN-bond with MePCl2 affords (2-Me2NC6H4)
