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Usage

InChI:InChI=1/C16H16/c1-13(2)12-15-10-6-7-11-16(15)14-8-4-3-5-9-14/h3-11H,1,12H2,2H3

Upstream product

• 1458-98-6 2-methyl-3-bromo-1-propene 
• 88284-48-4 2-(trimethylsilyl)phenyl trifluoromethanesulfonate 
• 98-80-6 phenylboronic acid 
• 2052-07-5 2-Bromobiphenyl 
• 107035-97-2 2,5-dimethyl-3-(1-methylethyl)-5-hexen-3-ol 
• 563-47-3 3-Chloro-2-methylpropene 
• 23533-35-9 biphenyl-2-ylmagnesium iodide 

Relevant academic research and scientific papers

Highly efficient route to o-allylbiaryls via palladium-catalyzed three-component coupling of benzynes, allylic halides, and aryl organometallic reagents

(Chemical Equation Presented) o-Allylbiaryl derivatives have been prepared in good to excellent yields by the palladium-catalyzed three-component reaction of allyl halides, benzynes, and aryl organometallic reagents.

A N-heterocyclic tetracarbene Pd(II) moiety containing a Pd(II)-Pb(II) bimetallic MOF for three-component cyclotrimerization via benzyne

A novel Pd(ii)-Pb(ii) bimetallic metal-organic framework Pd(ii)-Pb(ii)-MOF (B) which contains an N-heterocyclic tetracarbene Pd(ii) moiety was synthesized based on a chelating N-heterocyclic dicarbene Pd(ii)-NHDC ligand (A) under solvothermal conditions. It can be a highly active heterogeneous catalyst for three-component cyclotrimerization via benzyne species.

Microwave-assisted palladium-catalyzed allylation of aryl halides with homoallyl alcohols via retro-allylation

The palladium-catalyzed allylation of aryl halides with homoallyl alcohols via retro-allylation proceeds at 200-250 °C in a toluene-DMF mixed solvent using microwave heating. Even at such high temperatures, the regio- and stereospecificity of the allyl tr