860772-24-3Relevant academic research and scientific papers
Hammett studies of aryldichloromethide carbanion reactions
Moss, Robert A.,Tian, Jingzhi
, p. 1245 - 1247 (2006)
Rate constants were measured for the capture of para-substituted phenylchlorocarbenes by chloride ions to form aryldichloromethide carbanions and for the additions of these carbanions to acrylonitrile. Hammett analyses give ρ = +0.86 for the former reacti
Concurrent cyclopropanation by carbenes and carbanions
Moss, Robert A.,Tian, Jingzhi
, p. 8960 - 8961 (2007/10/03)
The generation of phenylhalocarbenes in the presence of varying quantities of halide ions and electron-poor alkenes affords concurrent cyclopropanation of the alkenes by an equilibrating mixture of phenylhalocarbenes and phenylhalomethide carbanions, whic
CHLOROACRYLONITRILE, A DETECTOR SUBSTRATE FOR CARBENE NUCLEOPHILICITY; APPLICATIONS TO PHENYLHALOCABENES
Moss, Robert A.,Fan, Hong,Hadel, Linda M.,Shen, Shilan,Wlostowska, Joanna,et al.
, p. 4779 - 4782 (2007/10/02)
α-Chloroacrylonitrile is an excellent substrate for nucleophilic and ambiphilic carbenes; its use permits visualization of the latent ambiphilic properties of the phenylhalocarbenes.
ARE PHENYLHALOCARBENES AMBIPHILIC?
Moss, Robert A.,Lawrynowicz, Witold,Hadel, Linda M.,Hacker, Nigel P.,Turro, Nicholas J.,et al.
, p. 4125 - 4128 (2007/10/02)
In additions to simple alkenes and styrenes at 25 deg C, the selectivities of PhCF and PhCCl are best described as electrophilic.
