861014-86-0Relevant academic research and scientific papers
Carbenium ions generated upon adsorption of 4-methoxystyrenes onto acid zeolites. A kinetic study
Fornes, Vicente,Garcia, Hermenegildo,Marti, Vicente,Fernandez, Lorenzo
, p. 3827 - 3832 (2007/10/03)
Adsorption of vinylanisole and trans-(4-methoxyphenyl)-1-propene into HY, Hβ and HZSM-5 allows us to detect the corresponding substituted 1,3- bis(4-methoxyphenyl)-1-propylium (2), 1-(4-methoxyphenyl)-6-methoxy-1- indanylium (5) and 1,3-bis(4-methoxyphenyl)-2-propen-1-ylium (8) cations as reactive intermediates. The kinetics can be followed by conventional spectrophotometers. Cation 2 appears as the shorter lived species, decaying in hours for the HY sample and within days when embedded in HZSM-5 zeolite. Cyclic indanyl cation 5 shows a-lifetime much longer than 2. A growth of 8 concomitantly with the decay of 2 has been also observed. This has been taken as a proof of a hydride transfer from neutral 1,3-bis(4-methoxyphenyl)-1- propenes (the corresponding acyclic dimers observed as products) as donors to cations 2 as acceptors leading to 8.
