86117-81-9

Upstream product

• 10226-79-6 DL-(1/2,3,4,5)-5-acethoxymethyl-1,2,3,4-tetra-O-acetyl-1,2,3,4-cyclohexanetetrol 
• 64716-98-9 2,3:4,7-di-O-isopropylidene-(1,2,3,5/4)-5-hydroxymethyl-1,2,3,4-cyclohexanetetrol 
• 74517-36-5 tetra-O-acetyl-(1,3,5/2,4)-2-bromo-5-hydroxymethyl-1,3,4-cyclohexanetriol 
• 64589-25-9 exo-2, endo-3-diacetoxy-endo-5-acetoxymethyl-7-oxabicyclo[2.2.1]heptane 
• 16656-59-0 Pseudo-β-DL-gulopyranose-triacetat; DL-1-Acetoxymethyl-2,5-diacetoxy-3,4-dihydroxy-cyclohexan 
• 16703-82-5 DL-2,5-Diacetoxy-1-acetoxymethyl-cyclohexen-⁽³⁾ 
• 10226-79-6 Pseudo-β-DL-gulopyranose-pentaacetat; DL-1-Acetoxymethyl-2,3,4,5-tetraacetoxy-cyclohexan 
• 900792-05-4 (1S,2R,5S,6S)-6-(acetyloxy)-2,5-dibromo-3-iodo-3-cyclohexenyl acetate 
• 320410-60-4 (1R,2R,3S,4S)-5-iodocyclohex-5-ene-1,2,3,4-tetraol 
• 165611-18-7 (3aS,4R,5R,7aS)-7-iodo-2,2-dimethyl-3a,4,5,7a-tetrahydro-1,3-benzodioxole-4,5-diol 
• 154784-39-1 (3aS,7aS)-4-iodo-2,2-dimethyl-3a,7a-dihydro-1,3-benzodioxole 
• 138769-92-3 cis-(1S,2S)-1,2-dihydroxy-3-iodocyclohexa-3,5-diene 
• 856890-25-0 (1R,4S,5R,6S)-4,5-di(benzoyloxy)-6-[{1-(tert-butyl)-1,1-dimethylsilyl}-oxy]-2-iodo-2-cyclohexenyl 4-nitrobenzoate 
• 856890-24-9 (1R,4S,5S,6S)-4,5-di(benzoyloxy)-6-hydroxy-2-iodo-2-cyclohexenyl 4-nitrobenzoate 

Downstream Products

• 10226-79-6 DL-(1,2/3,4,5)-5-acethoxymethyl-1,2,3,4-tetra-O-acetyl-1,2,3,4-cyclohexanetetrol 
• 97321-82-9 (1SR,3SR,5SR,8RS,10SR,12RS)-5,12-diphenyl-4,6,11,13-tetraoxatricyclo<8.3.0.0^3,8>tridecan-2-one 
• 97321-80-7 (1SR,2RS,3SR,5SR,8RS,10SR,12RS)-5,12-diphenyl-4,6,11,13-tetraoxatricyclo<8.3.0.0^3,8>tridecan-2-ol 
• 10226-73-0 DL-(1,5/2,3,4)-5-hydroxymethyl-1,2,3,4-cyclohexanetetrol 
• 10226-79-6 DL-(1,5/2,3,4)-5-acetoxymethyl-1,2,3,4-tetra-acetoxycyclohexane 
• 10226-73-0 (1R,2R,3S,4R,5R)-5-Hydroxymethyl-cyclohexane-1,2,3,4-tetraol 
• 64714-19-8 Toluene-4-sulfonic acid (3aR,4R,5aS,9aS,9bR)-2,2,8,8-tetramethyl-hexahydro-[1,3]dioxolo[4',5':3,4]benzo[1,2-d][1,3]dioxin-4-yl ester 
• 108813-47-4 (1S,2S,3R,4R,5S)-2,3,4,5-tetraacetoxy-1-(acetoxymethyl)cyclohexane, pseudo-β-L-glucopyranose pentaacetate 
• 10226-79-6 DL-(1,2,3,5/4)-5-acethoxymethyl-1,2,3,4-tetra-O-acetyl-1,2,3,4-cyclohexanetetrol 
• 117938-24-6 (2R,4aR,6R,7S,8S,8aR)-6,7,8-Tris-benzyloxy-2-phenyl-hexahydro-benzo[1,3]dioxine 
• 117902-50-8 (1RS,3RS,6RS,8RS,9SR,10SR)-8,9,10-trihydroxy-3-phenyl-2,4-dioxabicyclo<4.4.0>decane 
• 117938-24-6 (4aR,6S,7S,8S,8aR)-6,7,8-Tris-benzyloxy-2-phenyl-hexahydro-benzo[1,3]dioxine 
• 134428-47-0 6-O-acetyl-1,2,3-tri-O-benzyl-5a-carba-α-DL-glucopyranose 
• 125258-11-9 DL-(1,2,4/3,5)-1,2,3-tri-O-benzyl-5-hydroxymethyl-1,2,3,4-cyclohexanetetrol 

Relevant academic research and scientific papers

Chemoenzymatic synthesis of carbasugars from iodobenzene

The versatile enantiopure cis-dihydrodiol metabolite 1, formed by bacterial metabolism of iodobenzene, has been used for the synthesis of the pyranose carbasugars (pseudosugars) carba-β-D-altropyranose 2, carba-α-L- galactopyranose 3, carba-β-D-idopyranos

A norbornyl route to cyclohexitols: Structural diversity in fragmentation through functional group switching. Synthesis of α- and β- galactose, α-talose and α-fucopyranose carbasugars

A novel fragmentation sequence has been executed within the norbornane system, involving C1-C7 bond scission, to extract a versatile, highly functionalized cyclohexanoid moiety. Its further evolution towards a range-of carbasugars is described. (C) 2000 Elsevier Science Ltd.

Strain-Directed Bridge Cleavage of (Phenylsulfonyl)-7-oxabicycloheptane Derivatives: Application to the Total Synthesis of Carba-α-DL-glucopyranose

New methodology to prepare highly oxygenated cyclohexenylsulfones by regioselective β-elimination of (phenylsulfonyl)-7-oxabicycloheptane derivatives has been developed, and its application to the total synthesis of carba-α-DL-glucopyranose is desc

SYNTHESIS OF FOUR NEW DIASTEREOISOMERS OF DL-5-HYDROXYMETHYL-1,2,3,4-CYCLOHEXANETETROL

Four new diastereoisomers of the pseudo-sugar DL-5-hydroxymethyl-1,2,3,4-cyclohexanetetrol, having (1,2,3,4/5)- (2), (1,5/2,3,4)- (3), (1,2,3/4,5)- (4), and (1,2,4,5/3)-configurations (5), have been synthesised by unambiguous sequences from readily availa