86120-34-5

Upstream product

• 621-84-1 O-benzyl carbamate 

Downstream Products

• 86120-35-6 (3R,6S)-3,6-Dimethyl-1-oxo-3,6-dihydro-1H-1λ⁴-[1,2]thiazine-2-carboxylic acid benzyl ester 
• 125640-84-8 N-benzyloxycarbonylheptylamine 
• 86120-35-6 (3R,6R)-3,6-Dimethyl-1-oxo-3,6-dihydro-1H-1λ⁴-[1,2]thiazine-2-carboxylic acid benzyl ester 
• 70867-38-8 benzyl (2-phenylethyl)carbamate 
• 65095-17-2 N-(benzyloxycarbonyl)propylamine 
• 107972-73-6 (1R,4S)-2-Oxo-2λ⁴-thia-3-aza-bicyclo[2.2.2]oct-5-ene-3-carboxylic acid benzyl ester 
• 125640-83-7 benzyl isobutylcarbamate 
• 125640-86-0 benzyl cinnamylcarbamate 
• 125640-87-1 Cyclohex-3-enylmethyl-carbamic acid benzyl ester 
• 287205-61-2 Benzyl (1R,2S,4S)-2λ⁴-thia-3-azabicyclo[2.2.2]oct-5-ene-3-carboxylate 2-oxide 
• 786709-28-2 benzyl (1S,3R,6S)-3,6-dihydro-3,6-dimethyl-1λ⁴,2-thiazine-2-carboxylate 1-oxide 

Relevant academic research and scientific papers

3-Oxo-3-thia-2-azabicyclo[2.2.1]hept-5-en-2-carboxylates: The first isolation and characterization

Methyl and benzyl 3-oxo-3-thia-2-azabicyclo[2.2.1]hept-5-en-2-carboxylate were isolated at rt and characterized for the first time. Both endo and exo-isomers were observed. Under suitable experimental conditions (stoichiometric amount of sodium acetate, -40 °C or sodium borohydride/methyl iodide) ring opening of these compounds gave the corresponding thiosulfonates or methyl sulfides, respectively. 2012 Elsevier Ltd. All rights reserved.

NATURAL PRODUCT SYNTHESIS VIA CYCLOADDITIONS WITH N-SULFINYL DIENOPHILES

Diels-Alder cycloadducts derived from N-sulfinyl dienophiles have been used for stereospecific preparation of acyclic unsaturated amines and in stereospecific syntheses of threo-sphingosine (31) and erythro sphingosine (32).Methodology based upon these cy