861391-81-3Relevant academic research and scientific papers
Synthesis of functionalized 1-substituted alkenylsilanols and establishment of conditions for their palladium-catalyzed cross-coupling reactions to afford 1-substituted styrene derivatives
Ghosh, Sunil K.,Singh, Rekha,Singh, Gobind C.
, p. 4141 - 4147 (2004)
An efficient method for the quantitative conversion of 1-substituted alkenyl(phenyl)silanes into the corresponding alkenylsilanols has been developed and used in their palladium(0)-catalyzed, tetrabutylammonium fluoride-promoted cross-coupling reaction wi
A novel approach towards dibenzylbutyrolactone lignans involving heck and radical reactions: Application to (±)-matairesinol synthesis
Singh, Rekha,Singh, Gobind C.,Ghosh, Sunil K.
, p. 5376 - 5385 (2008/03/14)
A highly regio- and stereoselective Heck reaction of iodoarenes with vinylated malonates, generated in situ by fluoride-induced protiodesilylation of alkenylsilanols/disiloxanes to give functionalized styrenes and 1,4-diaryl-1-butenes has been developed. The dibenzylbutyrolactone lignan skeletons have been achieved from 1,4-diaryl-1-butenes by two routes involving diastereoselective radical cyclization as the key step. This strategy has successfully been applied in the synthesis of (±)-matairesinol. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.
A novel approach to functionalized (E)-1,4-diaryl-1-butenes by Heck reaction and their applications for the construction of dibenzylbutyrolactone lignan skeletons by radical cyclization
Singh, Rekha,Singh, Gobind C.,Ghosh, Sunil K.
, p. 4719 - 4722 (2007/10/03)
A highly regio- and stereoselective [Pd(allyl)Cl]2 catalyzed Heck reaction of aryl iodides and electronically neutral terminal olefins generated in situ by fluoride induced protiodesilylation of alkenylsilanol derivatives under mild conditions
