861682-76-0

Basic information

• Product Name: [RuH(CO)(P(C₆H₅)3)2(C₆H₄ClNCHC₆H₄O)]
• CAS NO: 861682-76-0
• Molecular Weight: 885.344
• Mol File: 861682-76-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [RuH(CO)(P(C₆H₅)3)2(C₆H₄ClNCHC₆H₄O)](CAS DataBase Reference)
• NIST Chemistry Reference: [RuH(CO)(P(C₆H₅)3)2(C₆H₄ClNCHC₆H₄O)](861682-76-0)
• EPA Substance Registry System: [RuH(CO)(P(C₆H₅)3)2(C₆H₄ClNCHC₆H₄O)](861682-76-0)

Safety Data

• Hazardous Substances Data: 861682-76-0(Hazardous Substances Data)

Upstream product

• 128817-71-0 [RuHCl(CO)(2,1,3-benzothiadiazole)(PPh₃)₂] 
• 3172-42-7 N-salicylidene-o-chloroaniline 

Relevant articles and documents

Ruthenium hydride and vinyl complexes supported by nitrogen-oxygen mixed-donor ligands

The Schiff base, 2-chlorophenylsalicylaldimine (HL1), is formed readily from salicylaldehyde and 2-chloroaniline. After deprotonation, this ligand is found to react as a bidentate mixed-donor chelate with the complexes [RuRCl(CO)(BTD)(PPh3)2] (R = H, CHCHC6H 5, CHCHC6H4Me-4, CHCHtBu, CCCPhCHPh; BTD = 2,1,3-benzothiadiazole) to form the compounds [RuR(L1)(CO) (PPh3)2] through displacement of the chloride and BTD ligands. An analogous reaction occurs with the osmium complex [OsHCl(CO)(BTD)(PPh3)2] to provide [OsH(L 1)(CO)(PPh3)2]. The compound [Ru(CHCHC 6H4Me-4)(L2)(CO)(PPh3)2] is formed through reaction of salicylaldehyde (HL2) with [Ru(CHCHC6H4Me-4)Cl(CO)(BTD)(PPh3) 2] in the presence of base. Two further ligands were investigated to extend the study to encompass 5- and 4-membered chelates; 8-hydroxyquinoline (HL3) and 2-hydroxy-4-methylquinoline (HL4) react with [Ru(CHCHPh)Cl(CO)(BTD)(PPh3)2] and [Ru(CHCHC 6H4Me-4)Cl(CO)(BTD)(PPh3)2] in the presence of base to yield the complexes [Ru(CHCHPh)(L3)(CO)(PPh 3)2] and [Ru(CHCHC6H4Me-4)(L 4)(CO)(PPh3)2], respectively. The crystal structure of [Ru(CHCHC6H4Me-4)(L1)(CO)(PPh 3)2] is reported.