86170-49-2

Basic information

• Product Name: 1-cyclooctyl-2-propanone
• Synonyms: 1-cyclooctyl-2-propanone
• CAS NO: 86170-49-2
• Molecular Weight: 168.279
• Mol File: 86170-49-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-cyclooctyl-2-propanone(CAS DataBase Reference)
• NIST Chemistry Reference: 1-cyclooctyl-2-propanone(86170-49-2)
• EPA Substance Registry System: 1-cyclooctyl-2-propanone(86170-49-2)

Safety Data

• Hazardous Substances Data: 86170-49-2(Hazardous Substances Data)

Upstream product

• 292-64-8 Cyclooctan 
• 65700-06-3 percarbonate de O,O-tert-butyle et O-isopropyle 

Relevant articles and documents

DECOMPOSITION DU PERCARBONATE DE O,O-t-BUTYLE ET O-ISOPROPENYLE EN SOLUTION DANS DES CYCLANES

Thermolysis of O,O-t-butyl and O-isopropenyl percarbonate in cyclohexane involves free-radical acetonylation of solvent.Free radicals derived from solvent add to the percarbonate double bond and after a double β-scission reaction, cyclohexylacetone carbon dioxide and t-butoxy radicals are formed.Abstracting H atoms from the solvent, t-butoxy radicals regenerate free radicals from solvent, and the reaction becomes a chain process.Extending the study to other cycloalkanes it has been shown that the process is a general synthesis method for cycloalkylacetones.On the other hand, competitive reactions of pairs of solvents have shown that the reactivity of the substrates depends on H atom lability and on more complex phenomena like transfers between hydrocarbons and C-centred free-radicals.