86171-08-6Relevant academic research and scientific papers
The Photochemical 1,5-Benzoyl Migration in 2,2-Diaryl-1,4,4-triphenyl-3-azabut-3-en-1-ones. A Novel Rearrangement in β,γ-Unsaturated Enone Systems
Armesto, Diego,Gallego, Mar G.,Horspool, William M.,Perez-Ossorio, Rafael
, p. 799 - 804 (2007/10/02)
The synthesis of 2,2-diphenyl- and 2,2-bis(p-chlorophenyl)-1,4,4-triphenyl-3-azabut-3-en-1-one is described.The photochemical reactivity of these compounds is described and interpreted in terms of 1,5-benzoyl migration, the terminus of which rearrangement is a phenyl ring.This type of reactivity is novel for β,γ-unsaturated systems.
