86172-89-6

Upstream product

• 25320-99-4 benzyl α-D-glucopyranoside 
• 83236-83-3 (2R,3S,4S,5R,6S)-6-Benzyloxy-5-trityloxy-2-trityloxymethyl-tetrahydro-pyran-3,4-diol 
• 100-44-7 benzyl chloride 
• 42926-92-1 benzyl 3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside 
• 58650-53-6 benzyl exo-2,3:4,6-di-O-benzylidene-α-D-mannopyranoside 
• 86342-12-3 benzyl 2-O-allyl-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside 
• 86353-43-7 benzyl 2-O-allyl-3,4-di-O-benzyl-α-D-mannopyranoside 

Downstream Products

• 86173-10-6 Acetic acid (2S,3R,4S,5R,6R)-6-acetoxymethyl-2,4,5-tris-benzyloxy-tetrahydro-pyran-3-yl ester 

Relevant academic research and scientific papers

Ditritylation of Methyl and Benzyl α-D-Gluco-, -Manno-, and -Galactopyranosides and Preparation of Their Partially Benzylated Derivatives

The ditritylation of methyl and benzyl α-D-gluco-, -manno-, and -galactopyranosides with trityl chloride in pyridine at 70 deg C proceeds in a regioselective manner to give the 2,6-ditrityl ethers of the glucosides, the 3,6-ones of the mannosides, and bot

CHEMO-, STEREO- AND REGIOSELECTIVE HYDROGENOLYSIS OF CARBOHYDRATE BENZYLIDENE ACETALS. SYNTHESIS OF BENZYL ETHERS OF BENZYL α-D-, METHYL β-D-MANNOPYRANOSIDES AND BENZYL α-D-RHAMNOPYRANOSIDE BY RING CLEAVAGE OF BENZYLIDENE DERIVATIVES WITH THE LiAlH4-AlCl3

Treatment of benzyl α-(1) and methyl β-D-mannopyranoside (2) with α,α-dimethoxytoluene gave the exo and endo isomers (3,5 and 4,6) of the dibenzylidene derivatives of 1 and 2.Hydrogenolysis of the exo isomers (3 and 5) with a molar equivalent of AlH2Cl ga