86172-98-7

Upstream product

• 108-24-7 acetic anhydride 
• 86179-47-7 2,6-di-O-trityl-α-D-glucopyranoside 
• 86172-78-3 (2R,3S,4S,5S,6S)-6-Methoxy-5-trityloxy-2-trityloxymethyl-tetrahydro-pyran-3,4-diol 
• 617-04-9 (2R,3S,4S,5S,6S)-2-(hydroxymethyl)-6-methoxytetrahydro-2H-pyran-3,4,5-triol 
• 76-83-5 trityl chloride 

Relevant academic research and scientific papers

Ditritylation of Methyl and Benzyl α-D-Gluco-, -Manno-, and -Galactopyranosides and Preparation of Their Partially Benzylated Derivatives

The ditritylation of methyl and benzyl α-D-gluco-, -manno-, and -galactopyranosides with trityl chloride in pyridine at 70 deg C proceeds in a regioselective manner to give the 2,6-ditrityl ethers of the glucosides, the 3,6-ones of the mannosides, and bot

REGIOSELECTIVE ALKYLATION via TRIALKYLSTANNYLATION: METHYL α-D-GLUCOPYRANOSIDE

Partial stannylation of methyl α-D-glucopyranoside with (Bu3Sn)2O, and subsequent alkylation with benzyl bromide, allyl bromide, and trityl chloride, afforded the 2,6-disubstituted derivative as one of major products in each case.