861899-24-3

Basic information

• Product Name: (S)-5-(4-methoxybenzyloxy)-4-methylpentanal
• Synonyms: (S)-5-(4-methoxybenzyloxy)-4-methylpentanal
• CAS NO: 861899-24-3
• Molecular Weight: 236.311
• Mol File: 861899-24-3.mol

Chemical Properties

• CAS DataBase Reference: (S)-5-(4-methoxybenzyloxy)-4-methylpentanal(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-5-(4-methoxybenzyloxy)-4-methylpentanal(861899-24-3)
• EPA Substance Registry System: (S)-5-(4-methoxybenzyloxy)-4-methylpentanal(861899-24-3)

Safety Data

• Hazardous Substances Data: 861899-24-3(Hazardous Substances Data)

Upstream product

• 123558-64-5 N-(4-methoxybenzyl)-2,2,2-trichloroacetamide 
• 212051-35-9 (R)-methyl 3-((4-methoxybenzyl)oxy)-2-methylpropanoate 
• 36394-07-7 5-hexenoyl chloride 
• 1577-22-6 5-hexenoic acid 
• 25913-88-6 (2S)-2-methyl-5-hexen-1-ol 
• 1251857-53-0 (S)-1-methoxy-4-(((2-methylhex-5-en-1-yl)oxy)methyl)benzene 
• 160238-46-0 (2R)-3-(4-methoxybenzyloxy)-2-methyl-1-propanal 
• 361543-13-7 (E)-(S)-5-(4-Methoxy-benzyloxy)-4-methyl-pent-2-enoic acid ethyl ester 
• 361543-15-9 (S)-5-(4-Methoxy-benzyloxy)-4-methyl-pentanoic acid ethyl ester 

Downstream Products

• 861899-31-2 (S)-3-((S,E)-7-(4-methoxybenzyloxy)-6-methylhept-2-enoyl)-4-benzyloxazolidin-2-one 
• 1251857-55-2 (4R,7S)-4-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)-7-methyloct-1-ene 
• 115566-02-4 bistramide A 
• 861899-38-9 (R)-3-((S,2E,7E,9E)-11-(4-methoxybenzyloxy)-6-methylundeca-2,7,9-trienoyl)-4-benzyloxazolidin-2-one 
• 861899-39-0 (S)-3-((S,2E,7E,9E)-11-(4-methoxybenzyloxy)-6-methylundeca-2,7,9-trienoyl)-4-benzyloxazolidin-2-one 
• 861899-15-2 3-((S,2E,7E,9E)-11-(4-methoxybenzyloxy)-6-methylundeca-2,7,9-trienoyl)oxazolidin-2-one 
• 861899-36-7 (R)-4-benzyl-3-((S,2E,7E)-8-iodo-6-methylocta-2,7-dienoyl)oxazolidin-2-one 
• 861899-37-8 (S)-4-benzyl-3-((S,2E,7E)-8-iodo-6-methylocta-2,7-dienoyl)oxazolidin-2-one 
• 861899-32-3 (R)-4-benzyl-3-((S,E)-7-hydroxy-6-methylhept-2-enoyl)oxazolidin-2-one 
• 861899-33-4 (S)-4-benzyl-3-((S,E)-7-hydroxy-6-methylhept-2-enoyl)oxazolidin-2-one 
• 861899-34-5 (E)-(S)-7-((R)-4-Benzyl-2-oxo-oxazolidin-3-yl)-2-methyl-7-oxo-hept-5-enal 
• 861899-35-6 (E)-(S)-7-((S)-4-Benzyl-2-oxo-oxazolidin-3-yl)-2-methyl-7-oxo-hept-5-enal 
• 861899-25-4 (S,E)-3-(7-(4-methoxybenzyloxy)-6-methylhept-2-enoyl)oxazolidin-2-one 
• 861899-30-1 (R)-3-((S,E)-7-(4-methoxybenzyloxy)-6-methylhept-2-enoyl)-4-benzyloxazolidin-2-one 

Relevant articles and documents

Total synthesis of bistramide A and its 36(Z) isomers: Differential effect on cell division, differentiation, and apoptosis

The total synthesis of bistramide A and its 36(Z),39(S) and 36(Z),39(R) isomers shows that these compounds have different effects on cell division and apoptosis. The synthesis relies on a novel enol ether-forming reaction for the spiroketal fragment, a kinetic oxa-Michael cyclization reaction for the tetrahydropyran fragment, and an asymmetric crotonylation reaction for the amino acid fragment. Preliminary biological studies show a distinct pattern of influence of each of the three compounds on cell division, differentiation, and apoptosis in HL-60 cells, thus suggesting that these effects are independent activities of the natural product. Copyright

Stereoselective synthesis of the C1-C13 fragment of bistramide A

The C1-C13 fragment of bistramide A was prepared from 5-hexenoic acid in 15 linear steps and in 16% overall yield. The core 2,6-trans-tetrahydropyran ring was obtained via a kinetically controlled oxa- Michael cyclization from the corresponding chiral α,β

A short approach to the bicyclo[4.3.0]nonane fragment of stawamycin

The bicyclo[4.3.0]nonane (C11-C21) fragment of stawamycin has been prepared by a sequence involving 11 steps (10% overall yield) from methyl (R)-(-)-3-hydroxy-2-methylpropionate. Key steps are a Pd-catalysed Stille coupling reaction