86201-74-3Relevant academic research and scientific papers
REACTION OF 2-ACYLPHENYLSELENOCYANATES WITH HYDROXYLAMINE AND PHENYLHYDRAZINE
Ames, D. E.,Singh, A. G.,Franklyn Smyth, W.
, p. 831 - 833 (2007/10/02)
2-Selenocyanatobenzophenone reacts with hydroxylamine to give 3-phenyl-1,2-benzisoselenazole N-oxide, the structure of which is indicated by polarographic reduction studies.The corresponding methyl and ethyl ketones react similarly but 3-methyl-2-selenocyanato acetophenone yields 4,8-dimethyl-2-imino-2H-1,3-benzoselenazine 3-oxide.Benzoselenophenoindole is formed under mild conditions by action of phenylhydrazine on 2-selenocyanatoacetophenone. 12H-Quinoxalinobenzoselenazine is obtained by condensation of 2,3-dichloroquinoxaline with the Zn salt of 2-aminobenzeneselenol.
