86210-81-3

Upstream product

• 71203-69-5 methyl 3-oxooctyl-7-enoate 
• 86210-75-5 (6S,7R)-7-Methoxycarbonylmethyl-6-methyl-1,4-dithia-spiro[4.5]decane-6-carboxylic acid methyl ester 
• 86210-68-6 (1S,2S)-2-Methoxycarbonylmethyl-1-methyl-6-oxo-cyclohexanecarboxylic acid methyl ester 
• 86210-66-4 (E)-8-Methyl-7-oxo-non-2-enedioic acid dimethyl ester 
• 344298-01-7 2-Methyl-3,7-dioxo-heptanoic acid methyl ester 
• 344298-00-6 2-Methyl-3-oxo-oct-7-enoic acid methyl ester 
• 91029-42-4 2-carboxy-2-methylcylohex-1-ylidenacetic acid 
• 101099-36-9 Ethyl 1-hydroxy-2-carbethoxy-2-methylcylohexanacetate 
• 102496-06-0 Ethyl 6-carbethoxy-6-methyl-1-cylohexen-1-ylacetate 
• 91029-44-6 6-carboxy-6-methyl-1-cylohexen-1-ylacetic acid 
• 26409-57-4 8a-methyl-1,3-dioxo-1,2,3,5,6,7,8,8a-octahydro-isoquinoline-4-carbonitrile 
• 91029-43-5 methyl 2-carbomethoxy-2-methylcylohex-1-ylidenacetate 
• 91029-45-7 methyl 6-carbethoxy-6-methyl-1-cylohexen-1-ylacetate 
• 186581-53-3 diazomethane 

Downstream Products

• 22920-01-0 trans-2-methyl-2-carboxy-cyclohexane-1-acetic acid 
• 22920-01-0 cis-2-methyl-2-carboxy-cyclohexane-1-acetic acid 

Relevant academic research and scientific papers

STEREOCHEMICAL CONTROL IN THE CONSTRUCTION OF VICINALLY SUBSTITUTED CYCLOPENTANES AND CYCLOHEXANES. INTRAMOLECULAR CONJUGATE ADDITION OF β-KETOESTER ANIONS.

The intramolecular addition of β-ketoesters to unsaturated enones and esters produces vicinally substituted carbocycles with high stereoselectivity.

Investigations on Reduction of 2-Carboxy-2-methylcyclohex-1-ylideneacetic Acid and Its Dimethyl Ester

The catalytic and chemical reductions of 2-carboxy-2-methylcyclohex-1-ylideneacetic acid (7)/its dimethyl ester (8) have been carried out as a model study.In these reduction studies, the mixture of cis- and trans-2-carboxy-2-methylcyclohexaneacetic acid (