862108-13-2

Basic information

• Product Name: 2,3,4-tri-O-benzoyl-α-L-rhamnopyranose
• Synonyms: 2,3,4-tri-O-benzoyl-α-L-rhamnopyranose
• CAS NO: 862108-13-2
• Molecular Weight: 476.483
• Mol File: 862108-13-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2,3,4-tri-O-benzoyl-α-L-rhamnopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,4-tri-O-benzoyl-α-L-rhamnopyranose(862108-13-2)
• EPA Substance Registry System: 2,3,4-tri-O-benzoyl-α-L-rhamnopyranose(862108-13-2)

Safety Data

• Hazardous Substances Data: 862108-13-2(Hazardous Substances Data)

Upstream product

• 61198-83-2 1,2,3,4-tetra-O-benzoyl-α/β-L-rhamnopyranose 
• 61198-83-2 1,2,3,4-tetra-O-benzoyl-6-desoxy-α-L-mannopyranose 

Downstream Products

• 161007-95-0 2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyltrichloroacetimidate 
• 616201-13-9 (2S,3R,4R,5S,6S)-2-(((3aS,6S,7R,7aS)-6-(allyloxy)-2,2-dimethyltetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-7-yl)oxy)-6-methyltetrahydro-2H-pyran-3,4,5-triyl tribenzoate 
• 616201-14-0 (2S,3R,4R,5S,6S)-2-(((2S,3R,4S,5S)-2-(allyloxy)-4,5-dihydroxytetrahydro-2H-pyran-3-yl)oxy)-6-methyltetrahydro-2H-pyran-3,4,5-triyl tribenzoate 
• 1044757-75-6 1-O-(4-azidobutyl)-4-O-(2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl)-2,3,5-tri-O-benzyl-D-ribitol 
• 1044757-74-5 1-O-(4-azidobutyl)-3-O-(2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl)-2,4,5-tri-O-benzyl-D-ribitol 
• 340964-54-7 allyl 2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl-(1->6)-3,4-di-O-benzoyl-α-D-glucopyranoside 

Relevant articles and documents

Practical synthesis of a tetrasaccharide derivative corresponding to ristomycin A and ristocetin A

A practical synthesis of fully benzoylated tetrasaccharide, whose free form is indispensable to the antibiotic ristomycin A for the process of dimerization and binding to the cell wall, was achieved via sequential assembly of the building blocks, allyl 3,4-di-O-benzoyl-α-D-glucopyranoside, 2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl trichloroacetimidate, 2-O-acetyl-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl trichloroacetimidate, and 2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl trichloroacetimidate. A one-pot preparation of allyl 3,4-di-O-benzoyl-2-O-tert-butyldimethylsilyl-6-O-triphenylmethyl-α-D- glucopyranoside is described, and regioselective glycosylation is carried out using perbenzoylated sugar trichloroacetimidates as glycosyl donors in the presence of a catalytic amount of trimethylsilyl trifluoromethanesulfonate (TMSOTf).