86211-03-2

Upstream product

• 88850-03-7 ((E)-1-Benzenesulfinyl-non-1-enyl)-trimethyl-silane 
• 88695-35-6 ((Z)-1-Benzenesulfinyl-non-1-enyl)-trimethyl-silane 
• 91083-84-0 N-Methyl-N-nitropelargonamide 
• 108-98-5 thiophenol 
• 19211-35-9 N-Methyl-N-nitrosopelargonamide 
• 86210-97-1 ((Z)-1-Chloro-non-1-enylsulfanyl)-benzene 
• 91083-85-1 N-Butyl-N-nitrosopelargonamide 
• 123431-76-5 C₁₃H₂₆N₂O₃ 
• 148237-55-2 Trimethyl-((Z)-1-phenylsulfanyl-non-1-enyl)-silane 
• 629-27-6 1-Iodooctane 
• 201230-82-2 carbon monoxide 
• 111-83-1 1-bromo-octane 
• 882-33-7 diphenyldisulfane 
• 329976-79-6 potassium trifluoro(n-octyl)borate 

Downstream Products

• 121782-10-3 [1-Eth-(Z)-ylidene-nonylsulfanyl]-benzene 
• 121782-11-4 [1-Eth-(E)-ylidene-nonylsulfanyl]-benzene 
• 141928-30-5 1-octen-2-yl phenyl sulfide 

Relevant academic research and scientific papers

Manganese(iii)-promoted thiocarbonylation of alkylborates with disulfides: synthesis of aliphatic thioesters

A Mn(iii)-promoted thiocarbonylation procedure toward the synthesis of thioesters has been developed. By employing easily available disulfides and potassium alkyltrifluoroborates as the starting materials, and cheap and non-toxic Mn(OAc)3·2H2O as the promotor, a broad range of thioesters were synthesized in good to excellent yieldsviaradical intermediates.

Rhodium-catalyzed carbonylative coupling of alkyl halides with thiols: a radical process faster than easier nucleophilic substitution

How to make a carbonylative coupling faster than the easier nucleophilic substitution? In this communication, a rhodium-catalyzed radical-based carbonylative coupling of alkyl halides with thiolphenols has been realized. Thioesters were isolated in good y

Conversion of Amides to S-Alkyl and S-Aryl Thioesters via Nitrosoamides and Nitroamides

Thiolates react at room temperature with nitrosoamides and, even more rapidly, with nitroamides to afford good yields of S-alkyl and S-aryl thioesters; by-products arising from N-to-S transnitrosations and transnitrations are practically not observed.

A HIGHLY CONVENIENT PROCEDURE FOR THE HYDROLYSIS OF TERMINAL PHENYL VINYL SULFIDES

Terminal vinyl and chlorovinyl sulfides are hydrolyzed by 70percent perchloric acid-thiophenol in benzene to the corresponding diphenyl thioacetals and thioesters in good yields.

SILA-PUMMERER REARRANGEMENTS AT SP2-HYBRIDIZED CARBON

α-Trimethylsilylvinyl sulfoxides undergo sila-Pummerer rearrangements upon warming in benzene.Alkynes, vinylsulfoxides, and ketene S,O-acetals are obtained as products.