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The chemical compound "(C5(CH3)5)Rh(P(CH3)3)2H+" is a rhodium-based organometallic complex. It features a rhodium atom at its center, which is bonded to two phosphorus atoms from two tri(methoxy)phosphine ligands (P(CH3)3). Additionally, the rhodium is also bonded to a pentamethylcyclopentadienyl ligand (C5(CH3)5), which is a type of cyclopentadienyl anion with five methyl groups attached to the carbon atoms. The overall charge of the complex is +1, indicating that it has lost one electron, making it a cation. (C5(CH3)5)Rh(P(CH3)3)2H(1+) is of interest in organometallic chemistry and catalysis due to its unique electronic properties and potential applications in various chemical transformations.

86224-86-4

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86224-86-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 86224-86-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,6,2,2 and 4 respectively; the second part has 2 digits, 8 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 86224-86:
(7*8)+(6*6)+(5*2)+(4*2)+(3*4)+(2*8)+(1*6)=144
144 % 10 = 4
So 86224-86-4 is a valid CAS Registry Number.

86224-86-4Downstream Products

86224-86-4Relevant academic research and scientific papers

Mechanism of carbon-fluorine bond activation by (C5Me5)Rh(PMe3)H2

Edelbach, Brian L.,Jones, William D.

, p. 7734 - 7742 (2007/10/03)

The complex Cp*Rh(PMe3)H2 (Cp* = C5Me5) reacts with C6F6, C6F5H, C12F10, or C10F8 in pyridine or 1:1 pyridine/benzene to give the C-F cleavage products Cp*Rh(PMe3)(aryl(F))H in high yield. Kinetic studies reveal that the reaction has autocatalytic character, and fluoride ion is shown to be responsible for the catalysis. The anion [Cp*Rh(PMe3)H]- reacts rapidly with C12F10 or C10F8 to give the same C-F cleavage products as Cp*Rh(PMe3)H2. A mechanism initiated by deprotonation of Cp*Rh(PMe3)H2 followed by nucleophilic attack of the resulting anion on the polyfluoroaromatic with subsequent loss of fluoride is proposed. The fluoride ion continues the cycle by deprotonating Cp*Rh(PMe3)H2.

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