862275-63-6

Basic information

• Product Name: but-3-enoic acid 1-(tert-butyl-diphenyl-silanyloxymethyl)-but-3-enyl ester
• Synonyms: but-3-enoic acid 1-(tert-butyl-diphenyl-silanyloxymethyl)-but-3-enyl ester
• CAS NO: 862275-63-6
• Molecular Weight: 408.613
• Mol File: 862275-63-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: but-3-enoic acid 1-(tert-butyl-diphenyl-silanyloxymethyl)-but-3-enyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: but-3-enoic acid 1-(tert-butyl-diphenyl-silanyloxymethyl)-but-3-enyl ester(862275-63-6)
• EPA Substance Registry System: but-3-enoic acid 1-(tert-butyl-diphenyl-silanyloxymethyl)-but-3-enyl ester(862275-63-6)

Safety Data

• Hazardous Substances Data: 862275-63-6(Hazardous Substances Data)

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 107033-46-5 (R)-(tert-butyldiphenylsilyloxy)methyloxirane 
• 625-38-7 but-3-enoic acid 
• 127793-64-0 (R)-1-O-(tert-butyldiphenylsilyl)-4-penten-1,2-diol 

Downstream Products

• 168777-39-7 (3aR,5R,6aR)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-tetrahydro-furo[3,2-b]furan-2-one 

Relevant articles and documents

4,5-Didehydro-7-silyloxymethyl-2-oxepanone and formal total syntheses of Hagen's gland lactones and trans-kumausynes

A concise and enantiospecific route to the 2,6-dioxabicyclo[3.3.0]octan-3-one ring system from commercially available (R)-(+)- and (S)-(-)-glycidols is described. The key features involve ring closing metathesis to construct the 7-substituted-4,5-dehydro-