86234-30-2Relevant academic research and scientific papers
The Prominent Effect of N6-Acyl Groups on the Reactivity of 9-Substituted Adenines: A New Method for the Chemical Modification of Adenines
Maki, Yoshifumi,Kameyama, Keiji,Suzuki, Mikio,Sako, Magoichi,Hirota, Kosaku
, p. 3601 - 3654 (2007/10/02)
The effect of various N6-substituents on the C(8)-hydrogen exchange of 9-substituted adenines has been estimated.The kinetic data clearly demonstrate that the N6-acyl groups significantly accelerate the C(8)-hydrogen exchange.This fa
FACILE HOMOLYTIC SUBSTITUTION OF N(6)-BENZOYLADENOSINES
Maki, Yoshifumi,Kameyama, Keiji,Sako, Magoichi,Hirota, Kosaku
, p. 799 - 802 (2007/10/02)
Contrary to adenosine, N(6)-benzoyl-2',3',5'-tri-O-acetyladenosine 1 undergoes smoothly homolytic methylation, hydroxymethylation, acylation, and carbamoylation in the acidic medium at the C(8)-position and subsequently at the C(2)-position.
