86254-98-0Relevant academic research and scientific papers
New cyclohexadienone derivatives: Preparation and chiral discrimination in high-pressure diels - Alder cycloadditions
Tran-Huu-Dau, Marie-Elise,Wartchow, Rudolf,Winterfeldt, Ekkehard,Wong, Yung-Sing
, p. 2349 - 2369 (2007/10/03)
A wide range of cyclohexadienones has been synthesised in order to study their reactivity and their regio- and stereoselectivity with the enantiopure diene 1 under high-pressure conditions. Computational investigations were used to point out some paramete
ADDITION OF FUNCTIONALIZED ORGANOLITHIUM REAGENTS TO p-BENZOQUINONES AND CYCLOHEXADIENONES: SYNTHESIS OF FUNCTIONALIZED CYCLOHEXADIENONES, DIENOLS AND DIENEDIOLS
Fischer, Alfred,Henderson, George Narayanan
, p. 131 - 134 (2007/10/02)
Low temperature addition of functionalized alkyllithium reagents to p-benzoquinones produces 4-alkyl-4-hydroxycyclohexa-2,5-dienones, and reaction of excess of the reagents with quinones yields 1,4-dialkylcyclohexa-2,5-diene-1,4-diols.With 4-acetoxy-, 4-h
