862553-73-9

Upstream product

• 862553-53-5 (1S)-1-[[2S(2α,4aα,7α,8aβ)]-3-allyl-4,4,7-trimethyl-octahydrobenzo[e][1,3]oxazin-2-yl]-1-phenylbut-3-en-1-ol 
• 503004-90-8 (2S,4aS,7R,8aR)-(3-but-2-enyl-4,4,7-trimethyloctahydrobenzo[e][1,3]oxazin-2-yl)phenyl ketone 
• 848033-71-6 (2S,4aS,7R,8aR)-N-allyl-2-benzoyl-4,4,7-trimethyl-octahydrobenzo[e][1,3]oxazine 

Downstream Products

• 862553-80-8 (3S)-N-(8-mentholyl)-3-phenyl-2,3,4,7-tetrahydro-1H-azepin-3-ol 

Relevant academic research and scientific papers

Sequential diastereoselective addition of allylic and homoallylic grignard reagents to 2-Acyl-perhydro-1,3-benzoxazines and ring-closing Metathesis: An asymmetric route to azepin-3-ol and azocin-3-ol derivatives

Chiral 2-acyl-3-allyl-substituted perhydrobenzoxazines derived from (-)-8-aminomenthol react with allyl or homoallyl Grignard reagents to provide the corresponding tertiary alcohols in very good yields and with excellent diastereo-selectivities. The 1,8-