862582-72-7Relevant academic research and scientific papers
Structures and vibrational spectra of the N-benzoyl N′- dialkylthiourea derivative and their complexes with Hg(II)
Weiqun, Zhou,Wen, Yang,Lihua, Qiu,Yong, Zhang,Zhengfeng, Yu
, p. 89 - 95 (2005)
The complex Hg (MTCB)2 (MTCB=N-(morpholinothiocarbonyl) benzamide) and Hg (PTCB)2 (PTCB=N-(piperidylthiocarbonyl) benzamide) have been synthesized and characterized by elemental analysis, FT-IR, FT-Raman spectra and NMR methods. The complex, Hg (MTCB)2, crystallizes in the triclinic space group P1?, with Z=2. Unit cell parameters, a=10.3621(11) ?, b=11.5738(11) ?, c=12.7722(7) ?, α=64.493(8)°, β=66.132(8)°, γ=85.811(11)°, V=1254.7(2) ?3. The FT-Infrared and FT-Raman spectra were used in study of the structures of MTCB, PTCB and their complexes with mercury cation, which were agreement with the result of X-ray diffraction.
