862602-89-9

Upstream product

• 862603-59-6 (S)-1-((2S,4S)-2-Phenyl-[1,3]dioxan-4-yl)-propane-1,3-diol 
• 98-59-9 p-toluenesulfonyl chloride 
• 862603-51-8 6-(tert-butyl-diphenyl-silanyloxy)-hex-3-enoic acid methyl ester 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 862603-57-4 (S)-3-(tert-Butyl-diphenyl-silanyloxy)-1-((2S,4S)-2-phenyl-[1,3]dioxan-4-yl)-propan-1-ol 
• 862603-54-1 (3S,4S)-6-(tert-Butyl-diphenyl-silanyloxy)-hexane-1,3,4-triol 
• 862602-87-7 (4S,5S)-5-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-4-hydroxy-dihydro-furan-2-one 

Downstream Products

• 862603-61-0 Toluene-4-sulfonic acid (S)-3-((2S,4S)-2-phenyl-[1,3]dioxan-4-yl)-3-[(E)-2-((S)-toluene-4-sulfinyl)-vinyloxy]-propyl ester 
• 862603-95-0 (S)-3-((2R,13R)-2-(tert-Butyl-dimethyl-silanyloxy)-13-{(2S,5R,2'S,5'R)-5'-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-undecyl]-octahydro-[2,2']bifuranyl-5-yl}-13-hydroxy-tridecyl)-5-methyl-3-phenylsulfanyl-dihydro-furan-2-one 
• 862603-31-4 (S)-3-((E)-(2R,13R)-2-(tert-Butyl-dimethyl-silanyloxy)-13-{(2S,5R,2'S,5'R)-5'-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-undecyl]-octahydro-[2,2']bifuranyl-5-yl}-13-hydroxy-tridec-10-enyl)-5-methyl-3-phenylsulfanyl-dihydro-furan-2-one 
• 862604-04-4 (S)-3-((2R,11R)-2-(tert-Butyl-dimethyl-silanyloxy)-11-{(2S,5R,2'S,5'R)-5'-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-undecyl]-octahydro-[2,2']bifuranyl-5-yl}-11-hydroxy-undecyl)-5-methyl-3-phenylsulfanyl-dihydro-furan-2-one 
• 862603-35-8 (S)-3-((E)-(2R,11R)-2-(tert-Butyl-dimethyl-silanyloxy)-11-{(2S,5R,2'S,5'R)-5'-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-undecyl]-octahydro-[2,2']bifuranyl-5-yl}-11-hydroxy-undec-8-enyl)-5-methyl-3-phenylsulfanyl-dihydro-furan-2-one 
• 862604-08-8 (S)-3-((R)-13-{(2S,5R,2'S,5'R)-5'-[(S)-1-(tert-Butyl-dimethyl-silanyloxy)-undecyl]-octahydro-[2,2']bifuranyl-5-yl}-13-hydroxy-tridecyl)-5-methyl-3-phenylsulfanyl-dihydro-furan-2-one 
• 862603-47-2 (S)-3-((E)-(R)-13-{(2S,5R,2'S,5'R)-5'-[(S)-1-(tert-Butyl-dimethyl-silanyloxy)-undecyl]-octahydro-[2,2']bifuranyl-5-yl}-13-hydroxy-tridec-10-enyl)-5-methyl-3-phenylsulfanyl-dihydro-furan-2-one 
• 862603-02-9 Toluene-4-sulfonic acid (S)-3-{(2S,5R)-5-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-undecyl]-tetrahydro-furan-2-yl}-3-[(E)-2-((S)-toluene-4-sulfinyl)-vinyloxy]-propyl ester 
• 862603-70-1 tert-Butyl-[(S)-1-((2R,5S)-5-{(S)-3-iodo-1-[(E)-2-((S)-toluene-4-sulfinyl)-vinyloxy]-propyl}-tetrahydro-furan-2-yl)-undecyloxy]-dimethyl-silane 
• 862603-04-1 tert-Butyl-dimethyl-{(S)-1-[(2S,5R,2'S,5'R)-5'-((S)-toluene-4-sulfinylmethyl)-octahydro-[2,2']bifuranyl-5-yl]-undecyloxy}-silane 
• 862603-00-7 Toluene-4-sulfonic acid (S)-3-{(2S,5R)-5-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-undecyl]-tetrahydro-furan-2-yl}-3-hydroxy-propyl ester 
• 862603-66-5 tert-Butyl-dimethyl-{(S)-1-[(2R,5S)-5-((2S,4S)-2-phenyl-[1,3]dioxan-4-yl)-tetrahydro-furan-2-yl]-undecyloxy}-silane 
• 862602-98-0 (S)-1-[(2R,5S)-5-((2S,4S)-2-Phenyl-[1,3]dioxan-4-yl)-tetrahydro-furan-2-yl]-undecan-1-ol 
• 862602-92-4 (2S,4S)-4-{(S)-3-Iodo-1-[(E)-2-((S)-toluene-4-sulfinyl)-vinyloxy]-propyl}-2-phenyl-[1,3]dioxane 

Relevant academic research and scientific papers

Stereoselective syntheses of rolliniastatin 1, rollimembrin, and membranacin

A radical cyclization of β-alkoxyvinyl sulfoxides-Pummerer rearrangement-allylation protocol was successfully applied to the synthesis of the threol cis/threol cis/erythro bis-oxolane moiety in rolliniastatin 1 (1), rollimembrin (2), and membranacin (3).