862604-97-5Relevant academic research and scientific papers
Binuclear activation of cumulenes: Roles of the adjacent metals and the cumulene binding mode in the activation process
Ristic-Petrovic, Dusan,Anderson, D. Jason,Torkelson, Jeffrey R.,Ferguson, Michael J.,McDonald, Robert,Cowie, Martin
, p. 3711 - 3724 (2008/10/09)
The roles of the adjacent metals and the binding mode in the activation process of cumulenes were investigated. A binuclear complex was made to react with allene and methylallene to ultimately yield the vinylcarbene products. Nuclear magnetic resonance spectroscopy was used to monitor the reactions. It was proposed that the formation of the vinyl carbene products results from migration of the methyl ligand to the central cumulene carbon.
