86263-39-0Relevant academic research and scientific papers
Regioselective control in the oxidative cleavage of 4,6-o-benzylidene acetals of glycopyranosides by dimethyldioxirane
Stevenin, Arnaud,Boyer, Francois-Didier,Beau, Jean-Marie
supporting information; experimental part, p. 1783 - 1786 (2010/05/01)
"Chemical Equation Presentation" The oxidative cleavage of 4,6-O-benzylidene acetals of glycopyranosides using dimethyldioxirane (DMDO) leads to the corresponding hydroxy-benzoates in excellent yields. With a proper choice of the neighboring protecting groups, this oxidative fragmentation provides the 6- or 4-hydroxyl derivatives in a highly regioselective manner.
