86266-71-9Relevant articles and documents
Tertiobutylation de quelques cetones alicycliques et aliphatiques via leurs ethers d'enol trimethylsilyliques. Influence de l'environnement du carbonyle sur le deroulement de la reaction
Lion, Claude,Dubois, Jacques-Emile
, p. 375 - 379 (2007/10/02)
α-Tertiobutylation of aliphatic ketones via their trimethylsilyl enol ethers has been extended to the alicyclic series.A comparative study of the alkylation of ketones in both series with identical steric hindrance has been undertaken.The efficiency and limits of the reaction have been determinated by progressive substitution α and α' to the carbonyl.