862686-83-7

Basic information

• Product Name: [Ni₂(2,6-bis(N,N-di(2-pyridylmethyl)aminomethyl)-4-methylphenolate)(bis(p-nitrophenyl) phosphate)2]ClO₄
• CAS NO: 862686-83-7
• Molecular Weight: 1424.85
• Mol File: 862686-83-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ni₂(2,6-bis(N,N-di(2-pyridylmethyl)aminomethyl)-4-methylphenolate)(bis(p-nitrophenyl) phosphate)2]ClO₄(CAS DataBase Reference)
• NIST Chemistry Reference: [Ni₂(2,6-bis(N,N-di(2-pyridylmethyl)aminomethyl)-4-methylphenolate)(bis(p-nitrophenyl) phosphate)2]ClO₄(862686-83-7)
• EPA Substance Registry System: [Ni₂(2,6-bis(N,N-di(2-pyridylmethyl)aminomethyl)-4-methylphenolate)(bis(p-nitrophenyl) phosphate)2]ClO₄(862686-83-7)

Safety Data

• Hazardous Substances Data: 862686-83-7(Hazardous Substances Data)

Upstream product

• 4043-96-3 sodium bis(4-nitrophenyl) phosphate 
• 80528-41-2 2,6-bis[bis(2-pyridylmethyl)aminomethyl]-4-methylphenol 

Relevant articles and documents

Dinuclear Mn(II), Ni(II), and Zn(II) complexes bridged by Bis(p-nitrophenyl) phosphate ion: Relevance to bimetallic phosphodiesterase

2,6-Bis[N,N-di(2-pyridylmethyl)aminomethyl]-4-methylphenol (Hbpmp) has afforded dinuclear Mn(II), Ni(II), and Zn(II) complexes with two bis(p-nitrophenyl) phosphate (BNP-) ions, [M2(bpmp)(bnp) 2]ClO4 (M = Mn (1), Ni (2), Zn (3)). The structure of 1 · 2MeCN has been determined by the single crystal X-ray method. It has a dinuclear core structure bridged by the phenolic oxygen atom of bpmp- and two BNP- ions. Each metal center has a pseudo octahedral geometry with an average Mn-to-donor bond distance of 2.207 A. Physicochemical properties of 1-3 are studied and their relevance to biological phosphodiesterase is discussed.