86269-31-0

Basic information

• Product Name: Furan, 2,2',2''-methylidynetris[5-methyl-
• CAS NO: 86269-31-0
• Molecular Formula: C16H16O3
• Molecular Weight: 256.301
• Mol File: 86269-31-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Furan, 2,2',2''-methylidynetris[5-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Furan, 2,2',2''-methylidynetris[5-methyl-(86269-31-0)
• EPA Substance Registry System: Furan, 2,2',2''-methylidynetris[5-methyl-(86269-31-0)

Safety Data

• Hazardous Substances Data: 86269-31-0(Hazardous Substances Data)

Upstream product

• 534-22-5 2-methylfuran 
• 613-45-6 2,4-Dimethoxybenzaldehyde 
• 135-77-3 1,2,4-trimethoxy-benzene 
• 149-73-5 trimethyl orthoformate 

Downstream Products

• 1120-21-4 n-Undecane 
• 7249-32-3 6-pentylundecane 

Relevant articles and documents

UNUSUAL REACTION OF 2,4-DIMETHOXYBENZALDEHYDE AND 2-METHYLFURAN

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Polyfuryl(aryl)alkanes and their derivatives. 12. C-fur bond cleavage in the series of polyfuryl(aryl)alkanes

Reactions taking place with cleavage of the C-Fur bond are examined. It was established that disproportionation in two directions, leading to the formation of tris(5-methyl-2-furyl)methane, takes place when 3,4-dimethoxyphenylbis(5-methyl-2-furyl)methane is boiled in an acidic medium. The acid-catalyzed reaction of 5-methylfurfural with ethylene glycol leads to the formation of either 2-(5-methyl-2-furyl)-1,3-dioxolane or tris(5-methyl-2-furyl)methane, depending on the catalyst. The treatment of 2-(5-methyl-2-furyl)-1,3-dioxolane or gemtris(5·methyl-2-furyl)ethane with trityl perchlorate leads to tris(5-methyl-2-furyl)carbenium or bis(5-methyl-2-furyl)methylcarbenium perchlorates respectively. 1996 Plenum Publishing Corporation.