862884-85-3

Basic information

• Product Name: Cyclohexyl-[1-(3,3-dimethyl-oxiranyl)-meth-(Z)-ylidene]-amine
• Synonyms: Cyclohexyl-[1-(3,3-dimethyl-oxiranyl)-meth-(Z)-ylidene]-amine
• CAS NO: 862884-85-3
• Molecular Weight: 181.278
• Mol File: 862884-85-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cyclohexyl-[1-(3,3-dimethyl-oxiranyl)-meth-(Z)-ylidene]-amine(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexyl-[1-(3,3-dimethyl-oxiranyl)-meth-(Z)-ylidene]-amine(862884-85-3)
• EPA Substance Registry System: Cyclohexyl-[1-(3,3-dimethyl-oxiranyl)-meth-(Z)-ylidene]-amine(862884-85-3)

Safety Data

• Hazardous Substances Data: 862884-85-3(Hazardous Substances Data)

Upstream product

• 5369-62-0 (+/-)-3,3-dimethyloxirane-2-carboxaldehyde 
• 108-91-8 cyclohexylamine 
• 107-86-8 3,3-dimethyl acrylaldehyde 

Relevant articles and documents

Diastereoselective one-step synthesis of functionalized cis-aziridinyl alcohols from oxiranyl carbaldimines

(Chemical Equation Presented) Upon treatment with lithiumorganic nucleophiles, trans-configured oxiranyl carbaldimines are transformed into anti-configured cis-aziridinyl alcohols with excellent diastereoselectivity. This conversion may be explained by a new type of the aza-Payne rearrangement, including first a nucleophilic attack on the imine carbon atom with diastereofacial differentiation followed by an intramolecular nucleophilic opening of the oxiranyl ring with simultaneous formation of the aziridine ring.