862999-51-7Relevant articles and documents
Cp*(iPr3P)Ru(Cl)(η2-HSiClMe 2): The first complex with simultaneous Si-H and RuCl...SiCl inter-ligand inter actions
Osipov, Alexander L.,Vyboishchikov, Sergei F.,Dorogov, Konstantin Y.,Kuzmina, Lyudmila G.,Howard, Judith A. K.,Lemenovskii, Dmitrii A.,Nikonov, Georgii I.
, p. 3349 - 3351 (2005)
The addition of HSiMe2Cl to the unsaturated compound Cp*(iPr3P)RuCl gives an unstable adduct which, according to NMR (JH-Si = 33.5 Hz), X-ray crystal structure and DFT evidence, is a silane σ-complex Cp*(iPr 3P)Ru(Cl)(η2-HSiMe2Cl) supported by an unprecedented, simultaneous inter-ligand RuCl...SiCl hypervalent interaction between the chloride ligand on ruthenium and the SiMe2Cl group. The Royal Society of Chemistry 2005.