86305-83-1

Basic information

• Product Name: aquachloro(2,6-diacetylpyridine bis(benzoylhydrazone))manganese(II) chloride
• CAS NO: 86305-83-1
• Molecular Weight: 543.311
• Mol File: 86305-83-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: aquachloro(2,6-diacetylpyridine bis(benzoylhydrazone))manganese(II) chloride(CAS DataBase Reference)
• NIST Chemistry Reference: aquachloro(2,6-diacetylpyridine bis(benzoylhydrazone))manganese(II) chloride(86305-83-1)
• EPA Substance Registry System: aquachloro(2,6-diacetylpyridine bis(benzoylhydrazone))manganese(II) chloride(86305-83-1)

Safety Data

• Hazardous Substances Data: 86305-83-1(Hazardous Substances Data)

Upstream product

• 73818-26-5 (1,1’-(pyridine-2,6-diyl)bis(ethan-1-yl-1-ylidene))dibenzohydrazine 
• 7773-01-5 manganese(ll) chloride 

Relevant articles and documents

Investigation into Aroylhydrazones as Chelating Agents. Part 3. Synthesis and Spectroscopic Characterization of Complexes of MnII, CoII, NiII, CuII, and ZnII with 2,6-Diacetylpyridine Bis(benzoylhydrazone) and X-Ray Structure of Aquachloro<2,6-diacetylpyridine bis(benzoylhyd...

The chelating behaviour of neutral and deprotonated 2,6-diacetylpyridine bis(benzoylhydrazone) (H2dapb) has been investigated in some new complexes of MnII, CoII, NiII, CuII, and ZnII.An X-ray diffraction analysis was carried out on Cl.The crystals are monoclinic, space group P21/c, with unit-cell dimensions a = 7.065(6), b = 17.096(9), c = 19.446(13) Angstroem, β = 96.89(8) deg, and Z = 4.The structure was solved by the heavy-atom technique from 1545 observed independent reflections recorded at room temperature on an automated diffractometer and refined to a final R value of 0.0329.The structure consists of + cations and Cl- anions.The cation has a pentagonal-bipyramidal geometry, with H2dapb forming the equatorial plane and the H2O and Cl groups occupying the axial positions.The i.r. spectra suggest differences in the interaction of these metals with the hydrazone molecule.