86317-37-5

Basic information

• Product Name: 2-methyl-9-phenyl-4a-pyrrolidin-1-yl-1,2,3,4,4a,5,6,7,8,9,9a-decahydroxanthen
• CAS NO: 86317-37-5
• Molecular Weight: 351.532
• Mol File: 86317-37-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-methyl-9-phenyl-4a-pyrrolidin-1-yl-1,2,3,4,4a,5,6,7,8,9,9a-decahydroxanthen(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methyl-9-phenyl-4a-pyrrolidin-1-yl-1,2,3,4,4a,5,6,7,8,9,9a-decahydroxanthen(86317-37-5)
• EPA Substance Registry System: 2-methyl-9-phenyl-4a-pyrrolidin-1-yl-1,2,3,4,4a,5,6,7,8,9,9a-decahydroxanthen(86317-37-5)

Safety Data

• Hazardous Substances Data: 86317-37-5(Hazardous Substances Data)

Upstream product

• 39716-23-9 1-(4-methylcyclohex-1-en-1-yl)pyrrolidine 
• 5682-83-7 (E)-2-benzylidenecyclohexanone 

Relevant articles and documents

Dihydropyran Cycloadducts. Part 4. X-Ray and (13)C Nuclear Magnetic Resonance Studies on 2-Methyl-9-phenyl-4a-pyrrolidin-1-yl-1,2,3,4,4a,5,6,7,8,9a-decahydroxanthen

Based on X-ray data the relative configurations in the title compounds are as follows: the cyclohexene and dihydropyran rings are cis-fused and the 9-phenyl group is cis to the annelated hydrogen atom.This is the first evidence for previous assumptions that the ring closure of cyclic enamines with heterodiene systems results in a cis-ring junction.However, the position of the 9-phenyl group is in contrast to earlier results, established by (1)H n.m.r. and chemical methods.The products from the reaction of different cyclic enamines with 2-benzylidenecyclohexanone show the same stereochemistry according to (13)C n.m.r. investigations.