86319-81-5Relevant articles and documents
Derivatives of 1,3-Benzdioxoles, 48. Preparation and Reactions of 1,3-Benzdioxole-4,7-quinones
Dallacker, Franz,Holtmann, Bodo,Coerver, Wim
, p. 392 - 397 (2007/10/02)
We describe the preparation of a substituted 1,3-benzdioxole-4,7-quinone complex (2) by reaction of 4-hydroxy-1,3-benzdioxole (1) with potassiumnitrosodisulfonate.The quinones 4a-d can be obtained by treatment of the 4-hydroxy-7-methoxy-1,3-benzdioxoles 3a-d with ammoniumcerium(IV)nitrate.Reaction of 2 with several cyclophiles gives the addition compounds resp. the dehydrogenation-products 6b-d in partly high yields. - Keywords: 1,3-Benzdioxol-4,7-chinon, 6,7-Dimethyl-naphtho-1,3-dioxol-4,9-chinon, 6-Hydroxy-naphtho-1,3-dioxol-4,9-chinon