86333-63-3Relevant academic research and scientific papers
ALDOL ADDITIONS to α- AND β-ALKOXY ALDEHYDES : THE EFFECT OF CHELATION ON SIMPLE DIASTEREOSELECTIVITY
Reetz, M. T.,Kesseler, K.,Jung, A.
, p. 4327 - 4336 (1984)
The TiCl4 or SnCl4 mediated reaction of enol silanes with chiral α- or β-alkoxy aldehydes constitutes the only presently known, general way to perform aldol additions with chelation-control (asymmetric induction >90percent).If the enol silane is prochiral
