86342-17-8

Upstream product

• 86342-15-6 benzyl 2-O-allyl-3,4-di-O-benzyl-α-D-rhamnopyranoside 
• 603962-05-6 Toluene-4-sulfonic acid (2R,3R,4R,5S,6S)-3,4,6-tris-benzyloxy-5-hydroxy-tetrahydro-pyran-2-ylmethyl ester 
• 86353-43-7 benzyl 2-O-allyl-3,4-di-O-benzyl-α-D-mannopyranoside 
• 86342-12-3 benzyl 2-O-allyl-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside 
• 86342-13-4 benzyl 2-O-allyl-3,4-di-O-benzyl-6-O-(p-toluenesulfonyl)-α-D-mannopyranoside 
• 58650-53-6 benzyl exo-2,3:4,6-di-O-benzylidene-α-D-mannopyranoside 
• 42926-92-1 benzyl 3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside 

Downstream Products

• 603962-11-4 benzyl O-(2,3,4-tri-O-benzyl-α-D-rhamnopyranosyl)-(1->3)-O-(2,4-di-O-benzyl-α-D-rhamnopyranosyl)-(1->2)-3,4-di-O-benzyl-α-D-rhamnopyranoside 

Relevant academic research and scientific papers

Glycosylation using hemiacetal sugar derivatives: Synthesis of O-α-D-rhamnosyl-(1 → 3)-O-α-D-rhamnosyl-(1 → 2) -D-rhamnose and O-α-D-tyvelosyl-(1 → 3)-O-α-D-mannosyl-(1 → 4)-L-rhamnose

O-α-D-Rhamnopyranosyl-(1 → 3)-O-α-D-rhamnopyranosyl-(1 → 2)-D-rhamnopyranose, a repeating trisaccharide of the O-specific polysaccharides (OPSs) of Pseudomonades, and O-α-D-tyvelopyranosyl-(1 → 3)-O-α-D-mannopyranosyl-(1 → 4)-L-rhamnopyranose, a trisaccha

CHEMO-, STEREO- AND REGIOSELECTIVE HYDROGENOLYSIS OF CARBOHYDRATE BENZYLIDENE ACETALS. SYNTHESIS OF BENZYL ETHERS OF BENZYL α-D-, METHYL β-D-MANNOPYRANOSIDES AND BENZYL α-D-RHAMNOPYRANOSIDE BY RING CLEAVAGE OF BENZYLIDENE DERIVATIVES WITH THE LiAlH4-AlCl3

Treatment of benzyl α-(1) and methyl β-D-mannopyranoside (2) with α,α-dimethoxytoluene gave the exo and endo isomers (3,5 and 4,6) of the dibenzylidene derivatives of 1 and 2.Hydrogenolysis of the exo isomers (3 and 5) with a molar equivalent of AlH2Cl ga