86342-80-5Relevant articles and documents
Hexacarbonylmolybdenum(0)-Catalyzed Reductive Coupling of Allylic Acetates
Masuyama, Yoshiro,Otake, Kiyotaka,Kurusu, Yasuhiko
, p. 1527 - 1528 (2007/10/02)
The reaction of allylic acetates with zinc in the presence of a catalytic amount of hexacarbonylmolybdenum(0) led to reductive coupling for the formation of a 1,5-diene framework.Reductive coupling of nerolidyl acetate provided squalene and its isomers in high yield.
PALLADIUM-CATALYZED COUPLING OF ALLYLIC ACETATES WITH ZINC
Sasaoka, Shin-ichi,Yamamoto, Taku,Kinoshita, Hideki,Inomata, Katsuhiko,Kotake, Hiroshi
, p. 315 - 318 (2007/10/02)
Allylic acetates were coupled with zinc dust in the presence of a catalytic amount of to give the corresponding 1,5-dienes under mild conditions in high yields.Significant cosolvent effects were found with methanol or 1,2-ethanediol in tetrahydrofuran.