86347-10-6Relevant articles and documents
Superelectrophilic chemistry of imidazoles
Sheets, Matthew R.,Li, Ang,Bower, Edward A.,Weigel, Andrew R.,Abbott, Matthew P.,Gallo, Robert M.,Mitton, Adam A.,Klumpp, Douglas A.
experimental part, p. 2502 - 2507 (2009/07/25)
The mechanistic and synthetic chemistry of imidazole-based superelectrophiles has been studied. The protonated imidazole ring, or imidazolium group, is shown to enhance the electrophilic reactivity of an adjacent carboxonium group (compared to a related m