863582-11-0Relevant articles and documents
Synthesis of the western half of the lolicines and lolitrems
England, Dylan B.,Magolan, Jakob,Kerr, Michael A.
, p. 2209 - 2212 (2006)
The synthesis of the highly substituted indole portion of the complex tremorgenic natural products lolicine A and B is presented. The Diels-Alder reaction of a quinone monoimine enables the synthesis of an appropriately substituted indole. The key step in
Synthesis and cross-coupling reactions of substituted 5-triflyloxyindoles
England, Dylan B.,Kerr, Michael A.
, p. 6519 - 6522 (2007/10/03)
N-Arylsulfonyl quinone monoimines undergo smooth cycloadditions in a [4+2] sense to yield the expected cycloadducts. The crude cycloadducts, when subjected to a short series of simple transformations, produce synthetically useful quantities of 5-triflylox