863663-25-6

Basic information

• Product Name: 3,5-O-benzylidene-7-O-[tert-butyl(dimethyl)silyl]-1,4,6-trideoxy-2-C-((2R)-2-{(4S,5R)-5-[(1R)-1-hydroxyethyl]-4-methyl-4,5-dihydroisoxazol-3-yl}propyl)-4,6-dimethyl-2-O-(triethylsilyl)-L-glycero-D-gulo-heptitol
• Synonyms: 3,5-O-benzylidene-7-O-[tert-butyl(dimethyl)silyl]-1,4,6-trideoxy-2-C-((2R)-2-{(4S,5R)-5-[(1R)-1-hydroxyethyl]-4-methyl-4,5-dihydroisoxazol-3-yl}propyl)-4,6-dimethyl-2-O-(triethylsilyl)-L-glycero-D-gulo-heptitol
• CAS NO: 863663-25-6
• Molecular Weight: 678.113
• Mol File: 863663-25-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3,5-O-benzylidene-7-O-[tert-butyl(dimethyl)silyl]-1,4,6-trideoxy-2-C-((2R)-2-{(4S,5R)-5-[(1R)-1-hydroxyethyl]-4-methyl-4,5-dihydroisoxazol-3-yl}propyl)-4,6-dimethyl-2-O-(triethylsilyl)-L-glycero-D-gulo-heptitol(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-O-benzylidene-7-O-[tert-butyl(dimethyl)silyl]-1,4,6-trideoxy-2-C-((2R)-2-{(4S,5R)-5-[(1R)-1-hydroxyethyl]-4-methyl-4,5-dihydroisoxazol-3-yl}propyl)-4,6-dimethyl-2-O-(triethylsilyl)-L-glycero-D-gulo-heptitol(863663-25-6)
• EPA Substance Registry System: 3,5-O-benzylidene-7-O-[tert-butyl(dimethyl)silyl]-1,4,6-trideoxy-2-C-((2R)-2-{(4S,5R)-5-[(1R)-1-hydroxyethyl]-4-methyl-4,5-dihydroisoxazol-3-yl}propyl)-4,6-dimethyl-2-O-(triethylsilyl)-L-glycero-D-gulo-heptitol(863663-25-6)

Safety Data

• Hazardous Substances Data: 863663-25-6(Hazardous Substances Data)

Upstream product

• 79646-46-1 (R)-(-)-(Z)-pent-3-en-2-ol 

Downstream Products

• 863663-34-7 2-C-{(2R)-2-[(4S,5R)-5-acetyl-4-methyl-4,5-dihydroisoxazol-3-yl]propyl}-3,5-O-benzylidene-7-O-[tert-butyl(dimethyl)silyl]-1,4,6-trideoxy-4,6-dimethyl-2-O-(triethylsilyl)-L-glycero-D-gulo-heptitol 

Relevant articles and documents

Stereoselective synthesis of erythronolide A via nitrile oxide cycloadditions and related studies

(Chemical Equation Presented) An expeditious synthesis of erythronolide A is documented. Key steps of the approach include two magnesium-mediated nitrile oxide cycloadditions, a chelation-controlled Grignard reaction, and a Sharpless asymmetric dihydroxylation. 2009 American Chemical Society.