863664-87-3Relevant academic research and scientific papers
Efficient stereochemical controllers in biaryl Suzuki coupling reactions: Benzylic carbinols bearing in β-position thioether, dimethylamino, or sulfoxide groups
Broutin, Pierre-Emmanuel,Colobert, Francoise
, p. 3737 - 3740 (2007/10/03)
(Chemical Equation Presented) Highly atropo-diastereoselective Suzuki coupling between aryl halides bearing stereogenic benzylic carbinols with sulfoxide, thioether, or dimethylamino groups as efficient internal chelating ligands and 2-methoxy-1-naphthylboronic acid were performed with high yields; a palladacycle is proposed as a potential transition state.
