86368-19-6Relevant academic research and scientific papers
Reactions of 1-Halo-4-nitroanthraquinones with C-nucleophiles
Tabatskaya,Beregovaya
, p. 410 - 415 (2001)
1-Fluoro-4-nitroanthraquinone reacts with C-nucleophiles, yielding the corresponding fluorine replacement products. Reactions of 1-chloro-4-nitroanthraquinone with the same nucleophiles result in formation of mixtures of dechlorination and denitration pro
NUCLEOPHILIC ARYLATION OF DERIVATIVES OF NAPHTHO- AND ANTHRAQUINONES WITH 2,6-DI-tert-BUTYLPHENOL
Russkikh, S. A.,Klimenko, L. S.,Fokin, E. P.
, p. 144 - 149 (2007/10/02)
Derivatives of naphtho- and anthraquinones are arylated by sterically hindered 2,6-di-tert-butylphenol in DMSO with the addition of potassium carbonate or potassium hydroxide.The reaction takes place selectively at the para-carbon atom of the phenol, and the corresponding 3,5-di-tert-butyl-4-hydroxyphenyl derivatives of 1,4-naphthol- and 9,10-anthraquinones are formed.
